Summary of Reactions and Preferred Rate Data

Volume 2 - Organic Species

This file created on 01/03/2010.

For the list of authors, see the Committee Membership past and present.

Citation: Please cite the website as the most up-to-date version of this evaluated data summary table, together with the relevant publication: i.e. for this table please cite: R. Atkinson, D. L. Baulch, R. A. Cox, J. N. Crowley, R. F. Hampson, R. G. Hynes, M. E. Jenkin, M. J. Rossi, and J. Troe, Evaluated kinetic and photochemical data for atmospheric chemistry: Volume II - gas phase reactions of organic species, 2006, Atmos. Chem. Phys., 6, 3625-4055. http://www.atmos-chem-phys.net/6/3625/2006/ and http://www.iupac-kinetic.ch.cam.ac.uk/ . However, for selected data please give the relevant citation as noted in the final column of the table. Where the note in this final column is given in red, the current recommendation has been changed since the last publication. In brief, the key for the citation is as follows. 0: website only, 1: ACP Vol1, 2: ACP Vol 2, 3: ACP Vol3 and 4: ACP Vol4.

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Reactionk298

(cm3molecule-1s-1)		Δk298aTemp. Dependent Expression for k

(cm3molecule-1s-1)		Temp. range

(K)		Δ(E/R)a

(K)		Cite
O + CH3 → HCHO + H


1.1-101.1×10-10













O + CH3 → HCO + H2






O + CH3 → CO + H2 + H


2.2-112.2×10-11













Overall Reaction


1.3 -101.3 ×10-10



±0.1



1.3 ×10-10



290-900

±100

2
O(1D) + CH4 → HO + CH3


1.0-101.0×10-10













O(1D) + CH4 → CH3O or CH2OH + H


3.4-113.4×10-11













O(1D) + CH4 → HCHO + H2


7.5-127.5×10-12













Overall Reaction


1.5 -101.5 ×10-10



±0.10



1.5 ×10-10



200-350

±100

2
HO + CH4 → H2O + CH3


6.4 -156.4 ×10-15



±0.08



1.85 -12-1690 T1.85 ×10-12exp-1690/T



200-300

±100

2
HO + C2H2 + M → C2H2OH + M






5.1 -30N_2 [ N 2 ] 5.1 ×10-30N_2 [ N 2 ]

7.8 -137.8 ×10-13

1.0 -121.0 ×10-12

k0

1 bar of air

k∞

±0.1

±0.15

±0.3



5 -30 T300-1.5N_2 [ N 2 ] 5 ×10-30(T/300)-1.5N_2 [ N 2 ]





k0





298-800





Δn±1.5





2
Fc = 0.370.37
HO + C2H4 + M → C2H4OH + M






8.8 -29N_2 [ N 2 ] 8.8 ×10-29N_2 [ N 2 ]

7.9 -127.9 ×10-12

9.1 -129.1 ×10-12

k0

1 bar of air

k∞

±0.3



±0.3





8.6 -29 T300-3.1N_2 [ N 2 ] 8.6 ×10-29(T/300)-3.1N_2 [ N 2 ]



9.0 -12 T300-0.859.0 ×10-12(T/300)-0.85

k0



k∞

200-300



100-500

Δn±2



Δn±0.3

2
Fc = 0.480.48
HO + C2H6 → H2O + C2H5


2.4 -132.4 ×10-13



±0.08



6.9 -12-1000 T6.9 ×10-12exp-1000/T



200-300

±100

2
HO + C3H6 + M → C3H6OH + M






8.2 -27N_2 [ N 2 ] 8.2 ×10-27N_2 [ N 2 ]

2.9 -112.9 ×10-11

3.0 -113.0 ×10-11

k0

1 bar of air

k∞

±1.0



±0.1





8 -27 T300-3.5N_2 [ N 2 ] 8 ×10-27(T/300)-3.5N_2 [ N 2 ]



3.0 -11 T300-13.0 ×10-11(T/300)-1

k0



k∞

200-300



200-300

Δn±1



(Δlog k±0.1) Δn±1

2
Fc = 0.50.5
HO + C3H8 → H2O + CH3CH2CH2
HO + C3H8 → H2O + CH3CHCH3
Overall Reaction


1.1 -121.1 ×10-12



±0.08



7.6 -12-585 T7.6 ×10-12exp-585/T



200-300

±100

2
HO + CH3CH2CH2CH3 → H2O + CH2CH2CH2CH3
HO + CH3CH2CH2CH3 → H2O + CH3CHCH2CH3
Overall Reaction


2.35 -122.35 ×10-12



±0.06



9.8 -12-425 T9.8 ×10-12exp-425/T



180-300

±100

2

HO + CH2=C(CH3)CH=CH2(isoprene) → Products


1.0 -101.0 ×10-10



±0.06



2.7 -11390 T2.7 ×10-11exp390/T



240-430

±100

2
HO + alpha-Pinene → Products


5.3 -115.3 ×10-11



±0.15



1.2 -11440 T1.2 ×10-11exp440/T



290-430

±200

2
HO + CO → H + CO2
HO + CO + M → HOCO + M
Overall Reaction


1.44 -131N_2 [ N 2 ] 4.2 191.44 ×10(-13±0.05){1+N_2 [ N 2 ] 4.2 ×1019}

 0 to 1 bar of N_2

±0.05



1.44 -131N_2 [ N 2 ] 4.2 191.44 ×10(-13±0.1){1+N_2 [ N 2 ] 4.2 ×1019}

 0 to 1 bar of N_2

200-300

(Δlog k±0.1)

2
HO + HCHO → H2O + HCO


8.5 -128.5 ×10-12



±0.08



5.4 -12135 T5.4 ×10-12exp135/T



200-300

±100

2
HO + CH3CHO → H2O + CH3CO


1.4-111.4×10-11













HO + CH3CHO → H2O + CH2CHO


7.5-137.5×10-13













Overall Reaction


1.5 -111.5 ×10-11



±0.06



4.7 -12345 T4.7 ×10-12exp345/T



200-380

±80

2

HO + C2H5CHO → Products


1.9 -111.9 ×10-11



±0.10



4.9 -12405 T4.9 ×10-12exp405/T



240-380

±200

2

HO + CH3CH2CH2CHO → Products


2.4 -112.4 ×10-11



±0.10



6.0 -12410 T6.0 ×10-12exp410/T



250-430

±250

2
HO + CH2=C(CH3)CHO → Products


2.9 -112.9 ×10-11



±0.10



8.0 -12380 T8.0 ×10-12exp380/T



230-380

±200

2
OH + Pinonaldehyde → Products


3.9 -113.9 ×10-11



±0.15



5.2 -12600 T5.2 ×10-12exp600/T



290-380

±300

2

HO + (CHO)2 → H2O + HC(O)CO


9.7 -129.7 ×10-12



±0.1



3.1 -12340 T3.1 ×10-12exp340/T



200-300

±200

2

HO + HOCH2CHO → H2O + HOCH2CO


6.4-126.4×10-12













HO + HOCH2CHO → H2O + HOCHCHO


1.6-121.6×10-12













Overall Reaction


8.0 -128.0 ×10-12



±0.15



8.0 ×10-12



240-370

±200

2

HO + CH3C(O)CHO → H2O + CH3C(O)CO


1.3 -111.3 ×10-11



±0.15



1.9 -12575 T1.9 ×10-12exp575/T



220-410

±300

2

HO + CH3C(O)CH3 → H2O + CH2C(O)CH3


1.8 -131.8 ×10-13



±0.08



8.8 -12-1320 T1.7 -14423 T8.8 ×10-12exp-1320/T+1.7 ×10-14exp423/T



195-440

(Δlog k±0.08)

2
HO + CH3C(O)CH2CH3 → Products


1.1 -121.1 ×10-12



±0.10



1.5 -12-90 T1.5 ×10-12exp-90/T



210-300

±200

2

HO + CH3C(O)CH=CH2 → Products


2.0 -112.0 ×10-11



±0.10



2.6 -12610 T2.6 ×10-12exp610/T



230-380

±200

2
HO + CH3OH → H2O + CH2OH


7.7-137.7×10-13





HO + CH3OH → H2O + CH3O


1.3-131.3×10-13













Overall Reaction


9.0 -139.0 ×10-13



±0.08



2.85 -12-345 T2.85 ×10-12exp-345/T



210-300

±150

2
HO + C2H5OH → H2O + CH2CH2OH


1.6-131.6×10-13













HO + C2H5OH → H2O + CH3CHOH


2.8-122.8×10-12





HO + C2H5OH → H2O + CH3CH2O


1.6-131.6×10-13













Overall Reaction


3.2 -123.2 ×10-12



±0.06



3.0 -1220 T3.0 ×10-12exp20/T



210-300

±100

2
HO + CH3CH2CH2OH → Products


5.8 -125.8 ×10-12



±0.10



4.6 -1270 T4.6 ×10-12exp70/T



260-380

±100

2
HO + CH3CH(OH)CH3 → H2O + (CH3)2CHO
HO + CH3CH(OH)CH3 → H2O + CH3C(OH)CH3
HO + CH3CH(OH)CH3 → H2O + CH3CH(OH)CH2
Overall Reaction


5.1 -125.1 ×10-12



±0.08



2.6 -12200 T2.6 ×10-12exp200/T



250-360

±100

2
HO + CH3CH2CH2CH2OH → Products


8.5 -128.5 ×10-12



±0.15



5.3 -12140 T5.3 ×10-12exp140/T



260-380

±200

2
HO + CH3CH(OH)CH2CH3 → Products


8.7 -128.7 ×10-12



±0.15









2
OH + (CH3)2C(OH)CH=CH2 → Products


6.3 -116.3 ×10-11



±0.10



8.1 -12610 T8.1 ×10-12exp610/T



230-300

±200

2

HO + CH3OCH3 → H2O + CH3OCH2


2.8 -122.8 ×10-12



±0.08



5.7 -12-215 T5.7 ×10-12exp-215/T



230-300

±100

2
HO + 3-Methylfuran → Products


9.3 -119.3 ×10-11



±0.3









2
HO + CH3C(O)CH2OH → Products


4.5 -124.5 ×10-12



±0.25



1.6 -12-305 T1.6 ×10-12exp-305/T



230-370

±200

2

OH + (CH3)2C(OH)CHO → Products


1.4 -111.4 ×10-11



±0.2









2

HO + CH3OOH → H2O + CH2OOH




4.0-124.0×10-12

4.0-124.0×10-12











See data sheet



220-430



HO + CH3OOH → H2O + CH3OO


0.2-110.2×10-11





Overall Reaction


1.0 -111.0 ×10-11



±0.3



5.3 -12190 T5.3 ×10-12exp190/T



220-430

±200

2

HO + HC(O)OH → Products


4.5 -134.5 ×10-13



±0.15



4.5 ×10-13



290-450

±250

2
HO + CH3C(O)OH → H2O + CH2C(O)OH
HO + CH3C(O)OH → H2O + CH3C(O)O
Overall Reaction


6.9 -136.9 ×10-13



±0.10



4.0 -14850 T4.0 ×10-14exp850/T



220-300

±250

2

HO + C2H5C(O)OH → Products


1.2 -121.2 ×10-12



±0.2



1.2 ×10-12



290-450

±300

2
HO + CH3ONO2 → Products


2.3 -142.3 ×10-14



+0.5 -0.2



4.0 -13-845 T4.0 ×10-13exp-845/T



220-300

±400

2
HO + C2H5ONO2 → Products


1.8 -131.8 ×10-13



±0.3



6.7 -13-395 T6.7 ×10-13exp-395/T



230-300

±400

2
HO + 1-C3H7ONO2 → Products


5.8 -135.8 ×10-13

 1 bar air

±0.3









2
HO + 2-C3H7ONO2 → Products


2.9 -132.9 ×10-13



±0.2



6.2 -13-230 T6.2 ×10-13exp-230/T



230-300

±300

2
HO + 1-C4H9ONO2 → Products


1.6 -121.6 ×10-12



±0.2









2
HO + 2-C4H9ONO2 → Products


8.6 -138.6 ×10-13



±0.3









2
HO + CH3C(O)OONO2 → Products
<

3 -143 ×10-14













2
HO + CH3C(O)CH2ONO2 → Products
<

1 -121 ×10-12













2
HO + CH3CH2C(O)CH2ONO2 → Products


8.2 -138.2 ×10-13



±0.3









2
HO + CH3CH(ONO2)C(O)CH3 → Products


1.2 -121.2 ×10-12



±0.3









2
HO + CH2=C(CH3)C(O)OONO2(MPAN) → Products


2.9 -112.9 ×10-11



+0.2 -0.5









2
HO + HCN → Products


3 -143 ×10-14

 1 bar

±0.5



1.2 -13-400 T1.2 ×10-13exp-400/T

 1 bar

290-440

±300

2
HO + CH3CN → Products


2.2 -142.2 ×10-14

 1 bar

±0.15



8.1 -13-1080 T8.1 ×10-13exp-1080/T

 1 bar

250-390

±200

2
HO2 + CH3O2 → O2 + CH3OOH


4.7-124.7×10-12













HO2 + CH3O2 → O2 + HCHO + H2O




5.2-135.2×10-13

See data sheet

















Overall Reaction


5.2 -125.2 ×10-12



±0.2



3.8 -13780 T3.8 ×10-13exp780/T



205-580

±200

2

HO2 + HOCH2O2 → O2 + HOCH2O2H


6.0-126.0×10-12













HO2 + HOCH2O2 → O2 + HC(O)OH + H2O


3.6-123.6×10-12













HO2 + HOCH2O2 → O2 + HOCH2O


2.4-122.4×10-12













Overall Reaction


1.2 -111.2 ×10-11



±0.3



5.6 -152300 T5.6 ×10-15exp2300/T



275-335

±1500

2

HO2 + C2H5O2 → O2 + C2H5OOH


8.0 -128.0 ×10-12



±0.3



4.3 -13870 T4.3 ×10-13exp870/T



200-500

±400

2

HO2 + CH3C(O)O2 → O2 + CH3C(O)OOH


5.7-125.7×10-12













HO2 + CH3C(O)O2 → O3 + CH3C(O)OH


2.1-122.1×10-12













HO2 + CH3C(O)O2 → O2 + OH + CH3C(O)O


6.2-126.2×10-12













Overall Reaction


1.4 -111.4 ×10-11



±0.3



5.2 -13980 T5.2 ×10-13exp980/T



250-400

±500

2

HO2 + HOCH2CH2O2 → Products


1.2 -111.2 ×10-11



±0.2









2
HO2 + CH3OCH2O2 → O2 + CH3OCH2OOH
HO2 + CH3OCH2O2 → O2 + CH3OCHO + H2O
Overall Reaction
See data sheet2
HO2 + CH3C(O)CH2O2 → O2 + CH3C(O)CH2OOH


7.6-127.6×10-12













HO2 + CH3C(O)CH2O2 → O2 + HO + CH3C(O)CH2O


1.3-121.3×10-12













Overall Reaction


9.0 -129.0 ×10-12



±0.3









2

HO2 + HCHO → HOCH2OO


7.9 -147.9 ×10-14



±0.3



9.7 -15625 T9.7 ×10-15exp625/T



275-333

±600

2
HOCH2OO → HO2 + HCHO


1.5 21.5 ×102

s-1

±0.3



2.4 12-7000 T2.4 ×1012exp-7000/T



275-330

±2000

2
HO + (CH3)3CH → H2O + (CH3)3C
HO + (CH3)3CH → H2O + (CH3)2CHCH3
Overall Reaction


2.1 -122.1 ×10-12



±0.08



5.4 -12-285 T5.4 ×10-12exp-285/T



210-300

±150

0
HO + 2-Methylpropene → Products


5.1 -115.1 ×10-11



±0.10



9.4 -12505 T9.4 ×10-12exp505/T



290-430

±200

0
HO + 1-Butene → Products


3.1 -113.1 ×10-11



±0.08



6.6 -12465 T6.6 ×10-12exp465/T



290-430

±150

0
HO + cis-2-Butene → Products


5.6 -115.6 ×10-11



±0.10



1.1 -11485 T1.1 ×10-11exp485/T



290-430

±200

0
HO + trans-2-Butene → Products


6.4 -116.4 ×10-11



±0.10



1.0 -11553 T1.0 ×10-11exp553/T



290-430

±200

0
HO + CH3CH2OOH → H2O + CH3CHOOH
HO + CH3CH2OOH → H2O + CH2CH2OOH
HO + CH3CH2OOH → H2O + CH3CH2OO
Overall Reaction
>

6 -126 ×10-12













0
HO + CH3C(O)C(O)CH3 → Products


2.3 -132.3 ×10-13



±0.10



5.25 -13-243 T5.25 ×10-13exp-243/T



240-350

±50

0
HO + n-C3H7C(O)OH → Products


1.8 -121.8 ×10-12



±0.30









0
HO + i-C3H7CHO → Products


2.6 -112.6 ×10-11



±0.10



6.8 -12410 T6.8 ×10-12exp410/T



240-425

±60

0
HO + (CH3)2CHCH2OH → Products


8.9 -128.9 ×10-12



±0.08



2.73 -12352 T2.73 ×10-12exp352/T



240-370

±120

0
HO + (CH3)3COH → Products


1.1 -121.1 ×10-12



±0.08



1.6 -12-121 T1.6 ×10-12exp-121/T



240-314

±75

0
HO + HOCH2CH2OH → Products


1.45 -111.45 ×10-11



±0.20









0
HO + CH3CH(OH)CHO → Products


1.7 -111.7 ×10-11



±0.20









0
HO + CH3CH(OH)CH2OH → Products


2.1 -112.1 ×10-11



±0.20









0
HO + C6H6 → H2O + C6H5


8 -158 ×10-15



±0.5



3.8 -11-2520 T3.8 ×10-11exp-2520/T



330-1410

±300

HO + C6H6 → HOC6H6


1.2-121.2×10-12





Overall Reaction


1.2 -121.2 ×10-12



±0.10



2.3 -12-190 T2.3 ×10-12exp-190/T



230-350

±200

0
HO + C6H5CH3 → H2O + C6H5CH2


3.5 -133.5 ×10-13



±0.20



2.5 -11-1270 T2.5 ×10-11exp-1270/T



310-1050

±200

HO + C6H5CH3 → HOC6H5CH3


5.2-125.2×10-12





Overall Reaction


5.6 -125.6 ×10-12



±0.10



1.8 -12340 T1.8 ×10-12exp340/T



210-350

±200

0
HO + m-CH3C6H4OH → H2O + CH3C6H4O
HO + m-CH3C6H4OH → H2O + CH2C6H4OH
HO + m-CH3C6H4OH → CH3C6H4(OH)2
Overall Reaction


5.9 -115.9 ×10-11



±0.15



2.3 -12965 T2.3 ×10-12exp965/T



290-350

±600

0
HO + o-CH3C6H4OH → H2O + CH3C6H4O
HO + o-CH3C6H4OH → H2O + CH2C6H4OH
HO + o-CH3C6H4OH → CH3C6H4(OH)2
Overall Reaction


4.1 -114.1 ×10-11



±0.15



1.6 -12970 T1.6 ×10-12exp970/T



290-350

±600

0
HO + p-CH3C6H4OH → H2O + CH3C6H4O
HO + p-CH3C6H4OH → H2O + CH2C6H4OH
HO + p-CH3C6H4OH → CH3C6H4(OH)2
Overall Reaction


4.9 -114.9 ×10-11



±0.15



1.9 -12970 T1.9 ×10-12exp970/T



290-350

±600

0
HO + C6H5OH → H2O + C6H5O
HO + C6H5OH → H2O + C6H4OH
HO + C6H5OH → HOC6H5OH
Overall Reaction


2.8 -112.8 ×10-11



±0.15



4.7 -131220 T4.7 ×10-13exp1220/T



290-350

±600

0
HO + 1,2-dihydroxybenzene → Products


1.0 -101.0 ×10-10



±0.15









0
HO + 1,2-dihydroxy-3-methylbenzene → Products


2.0 -102.0 ×10-10



±0.15









0
HO + 1,2-dihydroxy-4-methylbenzene → Products


1.5 -101.5 ×10-10



±0.15









0
HO + 3-methyl-2-nitrophenol → Products


3.7 -123.7 ×10-12



±0.3









0
HO + 4-methyl-2-nitrophenol → Products


3.6 -123.6 ×10-12



±0.15









0
HO + 5-methyl-2-nitrophenol → Products


6.7 -126.7 ×10-12



±0.2









0
HO + 6-methyl-2-nitrophenol → Products


2.8 -122.8 ×10-12



±0.3









0
HO + 1,4-Benzoquinone → Products


4.6 -124.6 ×10-12



±0.15









0
HO + methyl-1,4-benzoquinone → Products


2.3 -112.3 ×10-11



±0.15









0
HO + C6H5NO2 → Products


1.4 -131.4 ×10-13



±0.5



6.0 -13-440 T6.0 ×10-13exp-440/T



250-370

±300

0
HO + 3-nitrotoluene → Products


1.2 -121.2 ×10-12



±0.5









0
HO + cis-CHOCH=CHCHO → Products


5.8 -115.8 ×10-11



±0.20









0
HO + trans-CHOCH=CHCHO → Products
≥

2 -112 ×10-11













0
HO + 3H-furan-2-one → Products


4.9 -114.9 ×10-11



±0.20









0
HO + Furan-2,5-dione → Products


1.4 -121.4 ×10-12



±0.20









0
HO + CH3C(O)CH=CHCHO(cisandtrans-4-oxopent-2-enal) → Products


6.2 -116.2 ×10-11



±0.20









0
HO + C6H5CHO(benzaldehyde) → Products


1.26 -111.26 ×10-11



±0.08



5.9 -12225 T5.9 ×10-12exp225/T



290-350

±170

0
HO + C6H5CH2OH(benzylalcohol) → Products


2.7 -112.7 ×10-11



±0.20









0
NO3 + CH4 → HNO3 + CH3
<

1 -181 ×10-18













2
NO3 + C2H2 → Products
<

1 -161 ×10-16













2
NO3 + C2H4 → Products


2.1 -162.1 ×10-16



±0.2



3.3 -12-2880 T3.3 ×10-12exp-2880/T



270-340

±500

2
NO3 + C2H6 → HNO3 + C2H5
<

1 -171 ×10-17













2
NO3 + C3H6 → Products


9.5 -159.5 ×10-15



±0.2



4.6 -13-1155 T4.6 ×10-13exp-1155/T



290-430

±300

2
NO3 + C3H8 → HNO3 + CH3CH2CH2
NO3 + C3H8 → HNO3 + CH3CHCH3
Overall Reaction
<

7 -177 ×10-17













2

NO3 + n-C4H10 → Products


4.6 -174.6 ×10-17



±0.2



2.8 -12-3280 T2.8 ×10-12exp-3280/T



290-430

±400

2
NO3 + CH2=C(CH3)CH=CH2(isoprene) → Products


7.0 -137.0 ×10-13



±0.2



3.15 -12-450 T3.15 ×10-12exp-450/T



250-390

±200

2
NO3 + alpha-Pinene → Products


6.2 -126.2 ×10-12



±0.10



1.2 -12490 T1.2 ×10-12exp490/T



260-390

±300

2
NO3 + HCHO → HNO3 + HCO


5.5 -165.5 ×10-16



±0.2









2
NO3 + CH3CHO → HNO3 + CH3CO


2.7 -152.7 ×10-15



±0.15



1.4 -12-1860 T1.4 ×10-12exp-1860/T



260-380

±500

2
NO3 + CH3CH2CHO → Products


6.3 -156.3 ×10-15



±0.15









2
NO3 + CH3CH2CH2CHO → Products


1.1 -141.1 ×10-14



±0.15



1.7 -12-1500 T1.7 ×10-12exp-1500/T



260-340

±500

2
NO3 + (CH3)2CHCHO → Products


1.25 -141.25 ×10-14



±0.2



1.67 -12-1460 T1.67 ×10-12exp-1460/T



260-420

±300

0
NO3 + CH2=C(CH3)CHO(methacrolein) → Products


3.4 -153.4 ×10-15



±0.15









2
NO3 + CH3C(O)CH=CH2(methylvinylketone) → Products
<

6 -166 ×10-16













2
NO3 + Pinonaldehyde → Products


2.0 -142.0 ×10-14



±0.25









2
NO3 + CH3C(O)CH3 → HNO3 + CH3C(O)CH2
<

3 -173 ×10-17













2
NO3 + 3-methylfuran → Products


1.9 -111.9 ×10-11



±0.5









2
NO3 + CH2=C(CH3)C(O)OONO2(MPAN) → Products


1.6 -161.6 ×10-16



±0.7









2
NO3 + CH3OH → Products


1.3 -161.3 ×10-16



±0.5



9.4 -13-2650 T9.4 ×10-13exp-2650/T



250-370

±700

2
NO3 + C2H5OH → Products
<

2 -152 ×10-15













2
NO3 + CH3CH(OH)CH3 → HNO3 + CH3C(OH)CH3


1.4-151.4×10-15













NO3 + CH3CH(OH)CH3 → HNO3 + CH2CH(OH)CH3






Overall Reaction


1.4 -151.4 ×10-15



±0.3









2
NO3 + CH3CH(OH)CH2CH3 → HNO3 + CH3C(OH)CH2CH3


2.0-152.0×10-15













NO3 + CH3CH(OH)CH2CH3 → HNO3 + CH2CH(OH)CH2CH3
NO3 + CH3CH(OH)CH2CH3 → HNO3 + CH3CH(OH)CHCH3
NO3 + CH3CH(OH)CH2CH3 → HNO3 + CH3CH(OH)CH2CH2
Overall Reaction


2.0 -152.0 ×10-15



±0.3









2

NO3 + (CH3)2C(OH)CH=CH2 → Products


1.2 -141.2 ×10-14



±0.2



4.6 -14-400 T4.6 ×10-14exp-400/T



260-400

±200

2
NO3 + 2-methylpropane → Products


1.1 -161.1 ×10-16



±0.15



3.0 -12-3050 T3.0 ×10-12exp-3050/T



290-430

±300

0
NO3 + 2-Methylpropene → Products


3.4 -133.4 ×10-13



±0.10









0
NO3 + 1-Butene → Products


1.3 -141.3 ×10-14



±0.10



3.2 -13-950 T3.2 ×10-13exp-950/T



230-480

±200

0
NO3 + cis-2-Butene → Products


3.5 -133.5 ×10-13



±0.15









0
NO3 + trans-2-Butene → Products


3.9 -133.9 ×10-13



±0.08



1.78 -12-530 T1.28 -14570 T1.78 ×10-12exp-530/T+1.28 ×10-14exp570/T



200-380

(Δlog k±0.08)

0
NO3 + C6H6 → Products
<

3 -173 ×10-17













0
NO3 + C6H5CH3 → Products


7.8 -177.8 ×10-17



±0.25









0
NO3 + m-CH3C6H4OH → CH3C6H4O + HNO3
NO3 + m-CH3C6H4OH → Products
Overall Reaction


1.0 -111.0 ×10-11



±0.15









0
NO3 + o-CH3C6H4OH → CH3C6H4O + HNO3
NO3 + o-CH3C6H4OH → Products
Overall Reaction


1.4 -111.4 ×10-11



±0.15









0
NO3 + p-CH3C6H4OH → CH3C6H4O + HNO3
NO3 + p-CH3C6H4OH → Products
Overall Reaction


1.1 -111.1 ×10-11



±0.15









0
NO3 + C6H5OH → C6H5O + HNO3
NO3 + C6H5OH → Products
Overall Reaction


3.8 -123.8 ×10-12



±0.15









0
NO3 + 1,2-dihydroxybenzene → Products


9.9 -119.9 ×10-11



±0.15









0
NO3 + 1,2-dihydroxy-3-methylbenzene → Products


1.7 -101.7 ×10-10



±0.15









0
NO3 + 1,2-dihydroxy-4-methylbenzene → Products


1.5 -101.5 ×10-10



±0.15









0
CH3 + O2 + M → CH3O2 + M






1.0 -30N_2 [ N 2 ] 1.0 ×10-30N_2 [ N 2 ]

1.8 -121.8 ×10-12

9.5 -139.5 ×10-13

k0

k∞

1 bar of air

±0.2

±0.3







1.0 -30 T300-3.3N_2 [ N 2 ] 1.0 ×10-30(T/300)-3.3N_2 [ N 2 ]

1.8 -12 T3001.11.8 ×10-12(T/300)1.1



k0

k∞



200-300

200-300



Δn±1

Δn±1



2
Fc = 0.270.27
CH3 + O3 → Products


2.3 -122.3 ×10-12



±0.3



4.7 -12-210 T4.7 ×10-12exp-210/T



240-400

±200

2
C2H5 + O2 → C2H4 + HO2




3.8 -153.8 ×10-15

1.9 -141.9 ×10-14

 1 bar of air

0.133 bar of air

±0.5

±0.5









2
C2H5 + O2 + M → C2H5O2 + M






6.1 -296.1 ×10-29

7.8 -127.8 ×10-12

7.0 -127.0 ×10-12

k0

k∞

1 bar of air

±0.3

±0.2







5.9 -29 T300-3.85.9 ×10-29(T/300)-3.8

7.8 -127.8 ×10-12



k0

k∞



200-300

200-300



Δn±1

(Δlog k±0.2)



2
Fc = 0.540.54
n-C3H7 + O2 + M → n-C3H7O2 + M




8 -128 ×10-12

6 -126 ×10-12

k∞

1 to 10 mbar of air

±0.2





8 -128 ×10-12



k∞



200-300



(Δlog k±0.2)



2
i-C3H7 + O2 + M → i-C3H7O2 + M


1.1 -111.1 ×10-11

k∞

±0.3



1.1 -111.1 ×10-11

k∞

200-300

(Δlog k±0.3)

2
1-C4H9 + O2 + M → 1-C4H9O2 + M


7.5 -127.5 ×10-12

k∞

±0.5









2
2-C4H9 + O2 + M → 2-C4H9O2 + M


1.7 -111.7 ×10-11

k∞

±0.5









2
CH3C(O)CH2 + O2 + M → CH3C(O)CH2O2 + M


1.2 -121.2 ×10-12

k∞

±0.2



7.2 -13130 T7.2 ×10-13exp130/T

k∞

291-520

±50

2

HCO + O2 → CO + HO2


5.2 -125.2 ×10-12



±0.15



5.2 ×10-12



200-300

±150

2

CH3CO + O2 + M → CH3C(O)O2 + M


5.1 -125.1 ×10-12

k∞

±0.2



5.1 -125.1 ×10-12

k∞

220-300

(Δlog k±0.2)

2
CH2OH + O2 → HCHO + HO2


9.7 -129.7 ×10-12



±0.10



5.5 -12155 T5.5 ×10-12exp155/T



250-500

±170

2

CH3CHOH + O2 → CH3CHO + HO2


1.9 -111.9 ×10-11



±0.3









2
CH2CH2OH + O2 → Products


3.0 -123.0 ×10-12



±0.3









2
CH3O + O2 → HCHO + HO2


1.9 -151.9 ×10-15



±0.2



7.2 -14-1080 T7.2 ×10-14exp-1080/T



290-610

±300

2
C2H5O + O2 → CH3CHO + HO2


8.1 -158.1 ×10-15



±0.2



2.4 -14-325 T2.4 ×10-14exp-325/T



295-354

±300

2