Summary of Reactions and Preferred Rate Data

Volume 4 - Organic Halogen Species

This file created on 01/03/2010.

For the list of authors, see the Committee Membership past and present.

Citation: Please cite the website as the most up-to-date version of this evaluated data summary table, together with the relevant publication: i.e. for this table please cite: R. Atkinson, D. Baulch, R. Cox, J. Crowley, R. Hampson, R. Hynes, M. Jenkin, M. Rossi, J. Troe, and T. Wallington, Evaluated Kinetic and Photochemical data for Atmospheric Chemistry:Volume IV - Gas-phase Reactions of Organic Halogen Species, 2008, Atmos. Chem. Phys., 8, 4141-4496. http://www.atmos-chem-phys.net/8/4141/2008/acp-8-4141-2008.html and http://www.iupac-kinetic.ch.cam.ac.uk/ . However, for selected data please give the relevant citation as noted in the final column of the table. Where the note in this final column is given in red, the current recommendation has been changed since the last publication. In brief, the key for the citation is as follows. 0: website only, 1: ACP Vol1, 2: ACP Vol 2, 3: ACP Vol3 and 4: ACP Vol4.

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Reactionk298

(cm3molecule-1s-1)		Δk298aTemp. Dependent Expression for k

(cm3molecule-1s-1)		Temp. range

(K)		Δ(E/R)a

(K)		Cite
O(1D) + COF2 → O(3P) + COF2


5.2-115.2×10-11













O(1D) + COF2 → Products


2.2-112.2×10-11





Overall Reaction


7.4 -117.4 ×10-11



±0.3









4
O(1D) + CH3F(HFC-41) → O(3P) + CH3F


2.7-112.7×10-11













O(1D) + CH3F(HFC-41) → Products


1.2-101.2×10-10





Overall Reaction


1.5 -101.5 ×10-10



±0.15









4
O(1D) + CH2F2(HFC-32) → O(3P) + CH2F2


3.6-113.6×10-11













O(1D) + CH2F2(HFC-32) → Products


1.5-111.5×10-11





Overall Reaction


5.1 -115.1 ×10-11



±0.3









4
O(1D) + CHF3(HFC-23) → O(3P) + CHF3


8.2-128.2×10-12













O(1D) + CHF3(HFC-23) → Products


0.9-120.9×10-12





Overall Reaction


9.1 -129.1 ×10-12



±0.15









4
O(1D) + CH3CH2F(HFC-161) → O(3P) + CH3CH2F


4.7-114.7×10-11













O(1D) + CH3CH2F(HFC-161) → Products


2.1-102.1×10-10





Overall Reaction


2.6 -102.6 ×10-10



±0.3









4
O(1D) + CH3CHF2(HFC-152a) → O(3P) + CH3CHF2


7.9-117.9×10-11













O(1D) + CH3CHF2(HFC-152a) → HO + Products


2.3-112.3×10-11













O(1D) + CH3CHF2(HFC-152a) → Products


7.9-117.9×10-11













Overall Reaction


1.8 -101.8 ×10-10



±0.20









4

O(1D) + CH3CF3(HFC-143a) → O(3P) + CH3CF3


8.1-128.1×10-12













O(1D) + CH3CF3(HFC-143a) → HO + Products


1.7-111.7×10-11













O(1D) + CH3CF3(HFC-143a) → Products


2.0-112.0×10-11













Overall Reaction


4.5 -114.5 ×10-11



±0.2









4

O(1D) + CH2FCF3(HFC-134a) → O(3P) + CH2FCF3


3.9-113.9×10-11













O(1D) + CH2FCF3(HFC-134a) → HO + Products


6.9-126.9×10-12













O(1D) + CH2FCF3(HFC-134a) → Products


2.9-122.9×10-12













Overall Reaction


4.9 -114.9 ×10-11



±0.1









4

O(1D) + CHF2CF3(HFC-125) → O(3P) + CHF2CF3
O(1D) + CHF2CF3(HFC-125) → HO + Products
O(1D) + CHF2CF3(HFC-125) → Products
Overall Reaction


1.2 -101.2 ×10-10



±0.3









4

HO + CH3F → H2O + CH2F


2.1 -142.1 ×10-14



±0.15



1.9 -12-1350 T1.9 ×10-12exp-1350/T



240-300

±400

4
HO + CH2F2 → H2O + CHF2


1.1 -141.1 ×10-14



±0.1



2.3 -12-1590 T2.3 ×10-12exp-1590/T



220-300

±200

4
HO + CHF3 → H2O + CF3


2.7 -162.7 ×10-16



±0.2



6.9 -13-2340 T6.9 ×10-13exp-2340/T



250-300

±300

4
HO + CF4 → HOF + CF3
<

2 -182 ×10-18













4
HO + CH3CH2F → H2O + CH3CHF


1.8-131.8×10-13













HO + CH3CH2F → H2O + CH2CH2F


0.3-130.3×10-13





Overall Reaction


2.1 -132.1 ×10-13



±0.2



2.7 -12-765 T2.7 ×10-12exp-765/T



210-300

±300

4
HO + CH3CHF2 → H2O + CH2CHF2
HO + CH3CHF2 → H2O + CH3CF2
Overall Reaction


3.6 -143.6 ×10-14



+0.10 -0.20



1.25 -12-1070 T1.25 ×10-12exp-1070/T



210-300

+200 -400

4
HO + CH3CF3 → H2O + CH2CF3


1.2 -151.2 ×10-15



±0.15



9.2 -13-1970 T9.2 ×10-13exp-1970/T



220-300

±300

4
HO + CH2FCH2F → H2O + CH2FCHF


1.0 -131.0 ×10-13



±0.3



1.5 -12-800 T1.5 ×10-12exp-800/T



210-300

±200

4
HO + CH2FCHF2 → H2O + CH2FCF2
HO + CH2FCHF2 → H2O + CHFCHF2
Overall Reaction


1.5 -141.5 ×10-14



±0.2



3.3 -12-1610 T3.3 ×10-12exp-1610/T



270-330

±300

4
HO + CH2FCF3 → H2O + CHFCF3


4.6 -154.6 ×10-15



±0.2



4.9 -13-1395 T4.9 ×10-13exp-1395/T



220-300

±300

4
HO + CHF2CHF2 → H2O + CF2CHF2


6.1 -156.1 ×10-15



±0.2



1.4 -12-1620 T1.4 ×10-12exp-1620/T



290-360

±300

4
HO + CHF2CF3 → H2O + CF2CF3


1.9 -151.9 ×10-15



±0.2



4.4 -13-1630 T4.4 ×10-13exp-1630/T



220-300

±300

4
HO + CHF2CF2CH2F → H2O + CHF2CF2CHF
HO + CHF2CF2CH2F → H2O + CF2CF2CH2F
Overall Reaction


7.7 -157.7 ×10-15



±0.3



2.2 -12-1685 T2.2 ×10-12exp-1685/T



285-365

±300

4
HO + CF3CF2CH2F → H2O + CF3CF2CHF


6.5 -156.5 ×10-15



±0.3



2.6 -13-1100 T2.6 ×10-13exp-1100/T



250-320

±400

4
HO + CF3CHFCHF2 → H2O + CF3CFCHF2
HO + CF3CHFCHF2 → H2O + CF3CHFCF2
Overall Reaction


5.0 -155.0 ×10-15



±0.3



1.4 -12-1680 T1.4 ×10-12exp-1680/T



290-380

±300

4
HO + CF3CH2CF3 → H2O + CF3CHCF3


3.3 -163.3 ×10-16



±0.3



1.3 -12-2465 T1.3 ×10-12exp-2465/T



270-340

±400

4
HO + CF3CHFCF3 → H2O + CF3CFCF3


1.4 -151.4 ×10-15



±0.2



5.3 -13-1770 T5.3 ×10-13exp-1770/T



250-380

±300

4
HO + CHF2OCHF2 → H2O + CHF2OCF2


2.2 -152.2 ×10-15



±0.1



1.9 -12-2020 T1.9 ×10-12exp-2020/T



270-460

±300

4
HO + HC(O)F → H2O + FCO
<

1.0 -141.0 ×10-14













4
HO + CHF2CHO → H2O + CHF2CO
HO + CHF2CHO → H2O + CF2CHO
Overall Reaction


1.6 -121.6 ×10-12



±0.2









4
HO + CF3CHO → H2O + CF3CO


5.8 -135.8 ×10-13



±0.2









4
HO + CF3C(O)OH → Products


1.3 -131.3 ×10-13



±0.1



1.3 -131.3 ×10-13



280-350

(Δlog k±0.1)

4
HO2 + CH2FO2 → O2 + CH2FO2H
HO2 + CH2FO2 → O2 + HCOF + H2O
Overall Reaction
See data sheet4
HO2 + CF3O2 → CF3O2H + O2
HO2 + CF3O2 → C(O)F2 + HOF + O2
Overall Reaction
See data sheet4
HO2 + CF3CHFO2 → O2 + CF3CHFO2H


4.3-124.3×10-12













HO2 + CF3CHFO2 → O2 + CF3C(O)F + H2O






Overall Reaction


4.3 -124.3 ×10-12



±0.2



2.0 -13910 T2.0 ×10-13exp910/T



210-365

±300

4
HO2 + CF3CF2O2 → O2 + CF3CF2O2H
HO2 + CF3CF2O2 → O2 + CF3C(O)F + HOF
Overall Reaction


1.2 -121.2 ×10-12



±0.5









4
FO2 + CO → Products
<

6 -166 ×10-16













4
FO2 + CH4 → Products
<

4.1 -154.1 ×10-15













4
CF3 + O2 + M → CF3O2 + M




2.3 -29N_2 [ N 2 ] 2.3 ×10-29N_2 [ N 2 ]

4 -124 ×10-12

k0

k∞

±0.1

±0.3





2.2 -29 T300-4.7N_2 [ N 2 ] 2.2 ×10-29(T/300)-4.7N_2 [ N 2 ]

4 ×10-12

k0

k∞

230-380

200-300

Δn±1.5

Δn±1.5

4
Fc = 0.390.39
CF3O + O2 → COF2 + FO2
<

1 -181 ×10-18





<

1 -10-5600 T1 ×10-10exp-5600/T



250-370



4
CF3O + O3 → CF3O2 + O2


1.8 -141.8 ×10-14



±1



2 -12-1400 T2 ×10-12exp-1400/T



250-370

±600

4
CF3O + H2O → CF3OH + HO
<

2 -172 ×10-17





<

3 -12-3600 T3 ×10-12exp-3600/T



250-380



4
CF3O + NO → COF2 + FNO


5.4 -115.4 ×10-11



±0.1



3.7 -11110 T3.7 ×10-11exp110/T



230-390

±100

4
CF3O + CH4 → CF3OH + CH3


2.2 -142.2 ×10-14



±0.1



2.6 -12-1420 T2.6 ×10-12exp-1420/T



230-380

±200

4
CF3O + C2H6 → CF3OH + C2H5


1.3 -121.3 ×10-12



±0.1



4.9 -12-400 T4.9 ×10-12exp-400/T



230-360

±200

4
CF3O2 + NO2 + M → CF3O2NO2 + M




5.6 -29N_2 [ N 2 ] 5.6 ×10-29N_2 [ N 2 ]

7.7 -127.7 ×10-12

k0

k∞

±0.2

±0.2





5.6 -29 T298-9N_2 [ N 2 ] 5.6 ×10-29(T/298)-9N_2 [ N 2 ]

7.7 -12 T298-0.677.7 ×10-12(T/298)-0.67

k0

k∞

200-300

260-300

Δn±3

Δn±0.5

4
CF3O2NO2 + M → CF3O2 + NO2 + M








4.5 -19N_2 [ N 2 ] 4.5 ×10-19N_2 [ N 2 ]

4.5 -19N_2 [ N 2 ] 4.5 ×10-19N_2 [ N 2 ]

6.0 -26.0 ×10-2

6.0 -26.0 ×10-2

k0 s-1

k0 s-1

k∞ s-1

k∞ s-1

±0.3

±0.3

±0.3

±0.3





2.5 -5-9430 TN_2 [ N 2 ] 2.5 ×10-5exp-9430/TN_2 [ N 2 ]

1.5 16-11940 T1.5 ×1016exp-11940/T



k0

k∞



260-300

260-300



±250

±250



4
Fc = 0.310.31
CH2FO2 + CH2FO2 → CH2FOH + HC(O)F + O2






CH2FO2 + CH2FO2 → CH2FO + CH2FO + O2


2.6-122.6×10-12













Overall Reaction


2.6 -122.6 ×10-12



±0.3



2.5 -13700 T2.5 ×10-13exp700/T



220-380

±300

4
CHF2O2 + CHF2O2 → CHF2OH + C(O)F2 + O2
CHF2O2 + CHF2O2 → CHF2O + CHF2O + O2
Overall Reaction
















4
CF3O2 + CF3O2 → CF3O + CF3O + O2


1.5 -121.5 ×10-12



±0.3









4
CF3O2 + CF3CHFO2 → CF3OH + CF3COF + O2
CF3O2 + CF3CHFO2 → CF3O + CF3CHFO + O2
Overall Reaction


8 -128 ×10-12



±0.5









4
CHF2CF2O2 + CHF2CF2O2 → CHF2CF2O + CHF2CF2O + O2
See data sheet4
CF3CHFO2 + CF3CHFO2 → CF3COF + CF3CHFOH + O2


See data sheet













CF3CHFO2 + CF3CHFO2 → CF3CHFO + CF3CHFO + O2


See data sheet













Overall Reaction


4.7 -124.7 ×10-12



±0.3



6.2 -13605 T6.2 ×10-13exp605/T



210-375

±200

4

CF3CF2O2 + CF3CF2O2 → CF3CF2O + CF3CF2O + O2
See data sheet4
HO + CF3CH2CH3(HFC-263fb) → CF3CH2CH2 + H2O
HO + CF3CH2CH3(HFC-263fb) → CF3CHCH3 + H2O
Overall Reaction


4.9 -144.9 ×10-14



±0.15



3.7 -12-1290 T3.7 ×10-12exp-1290/T



240-370

±300

0
HO + CF3CHFCH2F(HFC-245eb) → CF3CHFCHF + H2O
HO + CF3CHFCH2F(HFC-245eb) → CF3CFCH2F + H2O
Overall Reaction


1.6 -141.6 ×10-14



±0.15



1.1 -12-1250 T1.1 ×10-12exp-1250/T



240-380

±300

0
HO + CHF2CHFCHF2(HFC-245ea) → CHF2CHFCF2 + H2O
HO + CHF2CHFCHF2(HFC-245ea) → CHF2CFCHF2 + H2O
Overall Reaction


1.8 -141.8 ×10-14



±0.15



1.8 -12-1375 T1.8 ×10-12exp-1375/T



240-380

±300

0
HO + CF3CH2CHF2(HFC-245fa) → CF3CH2CF2 + H2O
HO + CF3CH2CHF2(HFC-245fa) → CF3CHCHF2 + H2O
Overall Reaction


6.9 -156.9 ×10-15



±0.12



6.0 -13-1331 T6.0 ×10-13exp-1331/T



270-370

±300

0
HO + CF3CH2CF2CH3(HFC-365mfc) → CF3CHCF2CH3 + H2O
HO + CF3CH2CF2CH3(HFC-365mfc) → CF3CH2CF2CH2 + H2O
Overall Reaction


7.1 -157.1 ×10-15



±0.2



1.6 -12-1620 T1.6 ×10-12exp-1620/T



270-380

±200

0
HO + CF3CH2CH2CF3(HFC-356mff) → CF3CHCH2CF3 + H2O


7.8 -157.8 ×10-15



±0.10



2.6 -12-1734 T2.6 ×10-12exp-1734/T



260-370

±300

0
HO + CF3CF2CH2CH2F(HFC-356mcf) → CF3CF2CHCH2F + H2O
HO + CF3CF2CH2CH2F(HFC-356mcf) → CF3CF2CH2CHF + H2O
Overall Reaction


4.2 -144.2 ×10-14



±0.15



1.7 -12-1108 T1.7 ×10-12exp-1108/T



250-370

±300

0
HO + CHF2CF2CF2CHF2(HFC-338pcc) → CF2CF2CF2CHF2 + H2O


4.3 -154.3 ×10-15



±0.08



7.82 -13-1548 T7.82 ×10-13exp-1548/T



230-420

±200

0
HO + CF3CH2CF2CH2CF3(HFC-458mfcf) → CF3CHCF2CH2CF3 + H2O


2.6 -152.6 ×10-15



±0.15



1.12 -12-1804 T1.12 ×10-12exp-1804/T



270-360

±300

0
HO + CF3CHFCHFCF2CF3(HFC-43-10mee) → CF3CFCHFCF2CF3 + H2O
HO + CF3CHFCHFCF2CF3(HFC-43-10mee) → CF3CHFCFCF2CF3 + H2O
Overall Reaction


3.3 -153.3 ×10-15



±0.15



5.68 -13-1534 T5.68 ×10-13exp-1534/T



240-400

(Δlog k±300)

0
HO + CF3CF2CH2CH2CF2CF3(HFC-55-10mcff) → CF3CF2CHCH2CF2CF3 + H2O


8.3 -158.3 ×10-15



±0.15









0
HO + CHF2(CF2)4CF3(HFC-52-13p) → CF2(CF2)4CF3 + H2O


1.8 -151.8 ×10-15



±0.10



5.76 -13-1726 T5.76 ×10-13exp-1726/T



250-430

±300

0
HO + CH2FCH2OH → CHFCH2OH + H2O
HO + CH2FCH2OH → CH2FCHOH + H2O
HO + CH2FCH2OH → CH2FCH2O + H2O
Overall Reaction


1.5 -121.5 ×10-12



±0.15



4.57 -12-330 T4.57 ×10-12exp-330/T



240-360

±200

0
HO + CHF2CH2OH → CF2CH2OH + H2O
HO + CHF2CH2OH → CHF2CHOH + H2O
HO + CHF2CH2OH → CHF2CH2O + H2O
Overall Reaction


3.6 -133.6 ×10-13



±0.25









0
HO + CF3CH2OH → CF3CHOH + H2O
HO + CF3CH2OH → CF3CH2O + H2O
Overall Reaction


1.1 -131.1 ×10-13



±0.06



1.90 -12-863 T1.90 ×10-12exp-863/T



250-430

±300

0
HO + CF3CH2CH2OH → CF3CHCH2OH + H2O
HO + CF3CH2CH2OH → CF3CH2CHOH + H2O
HO + CF3CH2CH2OH → CF3CH2CH2O + H2O
Overall Reaction


9.7 -139.7 ×10-13



±0.10









0
HO + C2F5CH2OH → C2F5CHOH + H2O
HO + C2F5CH2OH → C2F5CH2O + H2O
Overall Reaction


9.7 -149.7 ×10-14



±0.08



1.33 -12-780 T1.33 ×10-12exp-780/T



250-430

±300

0
HO + CF3CH(OH)CF3 → CF3C(OH)CF3 + H2O
HO + CF3CH(OH)CF3 → CF3CH(O)CF3 + H2O
Overall Reaction


2.5 -142.5 ×10-14



±0.12



6.90 -13-987 T6.90 ×10-13exp-987/T



250-430

±200

0
HO + CF3CHFCF2CH2OH → CF3CFCF2CH2OH + H2O
HO + CF3CHFCF2CH2OH → CF3CHFCF2CHOH + H2O
HO + CF3CHFCF2CH2OH → CF3CHFCF2CH2O + H2O
Overall Reaction


1.3 -131.3 ×10-13



±0.12



2.26 -12-848 T2.26 ×10-12exp-848/T



250-430

±300

0
HO + n-C3F7CH2OH → n-C3F7CHOH + H2O
HO + n-C3F7CH2OH → n-C3F7CH2O + H2O
Overall Reaction


9.4 -149.4 ×10-14



±0.15









0
HO + n-C4F9CH2OH → n-C4F9CHOH + H2O
HO + n-C4F9CH2OH → n-C4F9CH2O + H2O
Overall Reaction


9.4 -149.4 ×10-14



±0.15









0
HO + n-C4F9CH2CH2OH → n-C4F9CHCH2OH + H2O
HO + n-C4F9CH2CH2OH → n-C4F9CH2CHOH + H2O
HO + n-C4F9CH2CH2OH → n-C4F9CH2CH2O + H2O
Overall Reaction


1.0 -121.0 ×10-12



±0.15









0
HO + n-C6F13CH2CH2OH → n-C6F13CHCH2OH + H2O
HO + n-C6F13CH2CH2OH → n-C6F13CH2CHOH + H2O
HO + n-C6F13CH2CH2OH → n-C6F13CH2CH2O + H2O
Overall Reaction


8.3 -138.3 ×10-13



±0.15









0
HO + n-C8F17CH2CH2OH → n-C8F17CHCH2OH + H2O
HO + n-C8F17CH2CH2OH → n-C8F17CH2CHOH + H2O
HO + n-C8F17CH2CH2OH → n-C8F17CH2CH2O + H2O
Overall Reaction


9.2 -139.2 ×10-13



±0.15









0
HO + CF3CH(OH)2 → CF3C(OH)2 + H2O
HO + CF3CH(OH)2 → CF3CH(OH)O + H2O
Overall Reaction


1.2 -131.2 ×10-13



±0.20









0
HC(O)F + hv → Products
See data sheet4
C(O)F2 + hv → Products
See data sheet4
CF3CHO + hv → Products
See data sheet4
CF3C(O)F + hv → Products
See data sheet4
O(1D) + CHF2Cl → O(3P) + CHF2Cl


2.8-112.8×10-11













O(1D) + CHF2Cl → ClO + CHF2


5.5-115.5×10-11













O(1D) + CHF2Cl → Products


0.2-100.2×10-10





Overall Reaction


1.0 -101.0 ×10-10



±0.1



1.0 -101.0 ×10-10



170-350

(Δlog k±0.1)

4
O(1D) + CHFCl2 → ClO + CHFCl


1.4-101.4×10-10













O(1D) + CHFCl2 → Products


0.5-100.5×10-10





Overall Reaction


1.9 -101.9 ×10-10



±0.3



1.9 -101.9 ×10-10



180-350

(Δlog k±0.3)

4
O(1D) + CH3CF2Cl → O(3P) + CH3CF2Cl


5.7-115.7×10-11













O(1D) + CH3CF2Cl → Products


1.6-101.6×10-10





Overall Reaction


2.2 -102.2 ×10-10



±0.3









4
O(1D) + CH3CFCl2 → O(3P) + CH3CFCl2


8.1-128.1×10-12













O(1D) + CH3CFCl2 → Products


1.8-111.8×10-11





Overall Reaction


2.6 -112.6 ×10-11



±0.3









4
O(1D) + CH2ClCF3 → O(3P) + CH2ClCF3


2.4-112.4×10-11













O(1D) + CH2ClCF3 → Products


1-101×10-10





Overall Reaction


1.2 -101.2 ×10-10



±0.3









4
O(1D) + CH2ClCF2Cl → O(3P) + CH2ClCF2Cl
O(1D) + CH2ClCF2Cl → Products


1.6 -101.6 ×10-10



±0.5









Overall Reaction
See data sheet4
O(1D) + CHFClCF3 → O(3P) + CHFClCF3


2.7-112.7×10-11













O(1D) + CHFClCF3 → Products


5.9-115.9×10-11





Overall Reaction


8.6 -118.6 ×10-11



±0.3









4
O(1D) + CHCl2CF3 → O(3P) + CHCl2CF3


4.2-114.2×10-11













O(1D) + CHCl2CF3 → Products


1.6-101.6×10-10





Overall Reaction


2.0 -102.0 ×10-10



±0.3









4
O(1D) + CF2Cl2 → ClO + CF2Cl


1.2-101.2×10-10













O(1D) + CF2Cl2 → O(3P) + CF2Cl2


2.4-112.4×10-11













Overall Reaction


1.4 -101.4 ×10-10



±0.1



1.4 -101.4 ×10-10



170-350

(Δlog k±0.1)

4
O(1D) + CFCl3 → ClO + CFCl2


2.0-102.0×10-10













O(1D) + CFCl3 → O(3P) + CFCl3


3.0-113.0×10-11













Overall Reaction


2.3 -102.3 ×10-10



±0.1



2.3 -102.3 ×10-10



170-350

(Δlog k±0.1)

4
O(1D) + CCl4 → ClO + CCl3


2.9-102.9×10-10













O(1D) + CCl4 → O(3P) + CCl4


4.0-114.0×10-11













Overall Reaction


3.3 -103.3 ×10-10



±0.1



3.3 -103.3 ×10-10



200-350

(Δlog k±0.1)

4
O(1D) + COFCl → O(3P) + COFCl


1.9 -101.9 ×10-10



±0.3









4
O(1D) + COCl2 → O(3P) + COCl2
O(1D) + COCl2 → O(3P) + Cl2 + CO
O(1D) + COCl2 → Products
Overall Reaction




2.2 -102.2 ×10-10







±0.1





2.0 -1025 T2.0 ×10-10exp25/T



190-430

±25

4
Cl + HC(O)Cl → HCl + ClCO


7.5 -137.5 ×10-13



±0.08



1.12 -12-805 T1.12 ×10-12exp-805/T



220-330

±150

4

Cl + CH3OCl → Cl2 + CH3O


5.2-115.2×10-11













Cl + CH3OCl → HCl + CH2OCl


9.1-129.1×10-12













Overall Reaction


6.1 -116.1 ×10-11



±0.1









4
Cl + CH3F → HCl + CH2F


3.5 -133.5 ×10-13



±0.15



4.1 -12-735 T4.1 ×10-12exp-735/T



210-320

±400

4

Cl + CH3Cl → HCl + CH2Cl


4.8 -134.8 ×10-13



±0.1



2.3 -11-1150 T2.3 ×10-11exp-1150/T



220-360

±200

4
Cl + CH2F2 → HCl + CHF2


3.2 -143.2 ×10-14



±0.5



4.7 -12-1470 T4.7 ×10-12exp-1470/T



280-370

±500

4

Cl + CH2Cl2 → HCl + CHCl2


3.4 -133.4 ×10-13



±0.1



5.9 -12-850 T5.9 ×10-12exp-850/T



220-400

±200

4
Cl + CHF2Cl → HCl + CF2Cl


1.6 -151.6 ×10-15



±0.15



4.2 -12-2345 T4.2 ×10-12exp-2345/T



290-430

±400

4

Cl + CHFCl2 → HCl + CFCl2


2.0 -142.0 ×10-14



±0.2



5.5 -12-1675 T5.5 ×10-12exp-1675/T



290-430

±400

4
Cl + CH3CH2F → HCl + CH3CHF


6.5 -126.5 ×10-12



±0.3



1.0 -11-130 T1.0 ×10-11exp-130/T



280-370

±500

Cl + CH3CH2F → HCl + CH2CH2F


7.4 -137.4 ×10-13



±0.3



8.3 -12-720 T8.3 ×10-12exp-720/T



280-370

±500

Overall Reaction
See data sheet4
Cl + CH3CHF2 → HCl + CH3CF2


2.5 -132.5 ×10-13



±0.15



6.3 -12-965 T6.3 ×10-12exp-965/T



280-360

±500

Cl + CH3CHF2 → HCl + CH2CHF2


2.3 -152.3 ×10-15



±0.5



7.0 -12-2400 T7.0 ×10-12exp-2400/T



280-360

±500

Overall Reaction
See data sheet4
Cl + CH2FCH2F → HCl + CHFCH2F


7.0 -137.0 ×10-13



±0.2



2.5 -11-1065 T2.5 ×10-11exp-1065/T



280-360

±400

4
Cl + CH3CF3(HFC-143a) → HCl + CH2CF3


3.2 -173.2 ×10-17



±0.3



8.4 -12-3720 T8.4 ×10-12exp-3720/T



280-370

±500

4

Cl + CH2FCHF2(HFC-143) → HCl + CH2FCF2


2.5 -142.5 ×10-14



±0.5



3.3 -12-1450 T3.3 ×10-12exp-1450/T



280-370

±500

Cl + CH2FCHF2(HFC-143) → HCl + CHFCHF2


2.5 -142.5 ×10-14



±0.5



4.6 -12-1560 T4.6 ×10-12exp-1560/T



280-370

±500

Overall Reaction
See data sheet4
Cl + CH3CF2Cl(HCFC-142b) → HCl + CH2CF2Cl


4.1 -164.1 ×10-16



±0.15



1.4 -12-2420 T1.4 ×10-12exp-2420/T



296-440

±500

4
Cl + CH3CFCl2(HCFC-141b) → HCl + CH2CFCl2


2.1 -152.1 ×10-15



±0.1



1.7 -12-2000 T1.7 ×10-12exp-2000/T



298-376

±300

4
Cl + CH3CCl3 → HCl + CH2CCl3


8.5 -158.5 ×10-15



±0.2



3.5 -12-1790 T3.5 ×10-12exp-1790/T



298-418

±400

4

Cl + CH2FCF3(HFC-134a) → HCl + CHFCF3


1.5 -151.5 ×10-15



±0.08



2.3 -12-2190 T2.3 ×10-12exp-2190/T



260-430

±400

4

Cl + CHF2CHF2(HFC-134) → HCl + CF2CHF2


2.2 -152.2 ×10-15



±0.2



7.9 -12-2440 T7.9 ×10-12exp-2440/T



280-360

±500

4
Cl + CHF2CF3(HFC-125) → HCl + CF2CF3


2.5 -162.5 ×10-16



±0.15









4

Cl + CHFClCF3(HCFC-124) → HCl + CFClCF3


2.7 -152.7 ×10-15



±0.1



1.1 -12-1800 T1.1 ×10-12exp-1800/T



270-380

±500

4
Cl + CHCl2CF3(HCFC-123) → HCl + CCl2CF3


1.2 -141.2 ×10-14



±0.1



4.4 -12-1740 T4.4 ×10-12exp-1740/T



270-380

±500

4
HO + CH3Cl → H2O + CH2Cl


3.6 -143.6 ×10-14



±0.10



2.1 -12-1210 T2.1 ×10-12exp-1210/T



220-300

±200

4
HO + CH2FCl(HCFC-31) → H2O + CHFCl


3.9 -143.9 ×10-14



±0.10



1.6 -12-1105 T1.6 ×10-12exp-1105/T



240-300

±200

4
HO + CH2Cl2 → H2O + CHCl2


1.0 -131.0 ×10-13



±0.10



1.8 -12-860 T1.8 ×10-12exp-860/T



210-400

±150

4
HO + CHF2Cl(HCFC-22) → H2O + CF2Cl


4.7 -154.7 ×10-15



±0.08



7.9 -13-1530 T7.9 ×10-13exp-1530/T



240-300

±150

4
HO + CHFCl2(HCFC-21) → H2O + CFCl2


2.9 -142.9 ×10-14



±0.10



1.04 -12-1065 T1.04 ×10-12exp-1065/T



240-300

±200

4
HO + CHCl3 → H2O + CCl3


1.05 -131.05 ×10-13



±0.10



1.8 -12-850 T1.8 ×10-12exp-850/T



240-300

±300

4
HO + CF2Cl2(CFC-12) → HOCl + CF2Cl
<

1 -271 ×10-27





<

1 -10-11910 T1 ×10-10exp-11910/T



250-480



4

HO + CFCl3 → HOCl + CFCl2
<

5 -185 ×10-18





<

1 -10-9695 T1 ×10-10exp-9695/T



250-480



4

HO + CCl4 → HOCl + CCl3
<

1 -191 ×10-19





<

1 -10-6220 T1 ×10-10exp-6220/T



250-300



4

HO + C2HCl3 → Products


2.0 -122.0 ×10-12



±0.10



3.0 -13565 T3.0 ×10-13exp565/T



230-300

±200

4
HO + C2Cl4 → Products


1.6 -131.6 ×10-13



±0.10



3.5 -12-920 T3.5 ×10-12exp-920/T



290-420

±300

4
HO + CH3CF2Cl(HCFC-142b) → H2O + CH2CF2Cl


3.0 -153.0 ×10-15



±0.10



8.5 -13-1685 T8.5 ×10-13exp-1685/T



220-300

±200

4
HO + CH3CFCl2(HCFC-141b) → H2O + CH2CFCl2


5.8 -155.8 ×10-15



±0.10



8.1 -13-1470 T8.1 ×10-13exp-1470/T



220-300

±200

4
HO + CH3CCl3 → H2O + CH2CCl3


9.5 -159.5 ×10-15



±0.10



1.2 -12-1440 T1.2 ×10-12exp-1440/T



240-300

±200

4
HO + CH2ClCF3(HCFC-133a) → H2O + CHClCF3


1.4 -141.4 ×10-14



±0.25



4.9 -13-1065 T4.9 ×10-13exp-1065/T



260-380

±200

4

HO + CH2ClCF2Cl(HCFC-132b) → H2O + CHClCF2Cl


1.7 -141.7 ×10-14



±0.15



3.5 -12-1585 T3.5 ×10-12exp-1585/T



250-350

±300

4
HO + CHFClCF3(HCFC-124) → H2O + CFClCF3


8.7 -158.7 ×10-15



±0.20



3.5 -13-1105 T3.5 ×10-13exp-1105/T



210-300

±300

4
HO + CHCl2CF3(HCFC-123) → H2O + CCl2CF3


3.6 -143.6 ×10-14



±0.10



6.6 -13-870 T6.6 ×10-13exp-870/T



210-300

±200

4
HO + CHFClCF2Cl(HCFC-123a) → H2O + CFClCF2Cl


1.2 -141.2 ×10-14



±0.3



8.4 -13-1255 T8.4 ×10-13exp-1255/T



298-460

±400

4
HO + CHCl2CF2Cl(HCFC-122) → H2O + CCl2CF2Cl


5.1 -145.1 ×10-14



±0.2



8.1 -13-825 T8.1 ×10-13exp-825/T



270-340

±200

4
HO + CHFClCFCl2(HCFC-122a) → H2O + CFClCFCl2


1.6 -141.6 ×10-14



±0.3



5.8 -13-1065 T5.8 ×10-13exp-1065/T



270-340

±400

4
HO + CHCl2CF2CF3(HCFC-225ca) → H2O + CCl2CF2CF3


2.5 -142.5 ×10-14



±0.15



1.1 -12-1130 T1.1 ×10-12exp-1130/T



270-400

±300

4
HO + CHFClCF2CF2Cl(HCFC-225cb) → H2O + CFClCF2CF2Cl


8.9 -158.9 ×10-15